Methyl Orange Degradation using TiO2 Powder and Immobilized TiO2 Photocatalysts
DOI:
https://doi.org/10.46754/umtjur.v1i4.92Keywords:
Methyl orange, TiO2, nanotubes, immobilized, photocatalystAbstract
Methyl orange is one of the anionic dyes and is a major pollutant from textile industry that enters both aquatic and atmospheric systems. In this research, methyl orange was degraded using TiO2 powder and immobilized TiO2 on glass. Titanium tetra-isopropoxide (TTIP) was used for preparation of TiO2 powder using soft chemistry method, and it was immobilized on glass via paste-gel coating method. The prepared photocatalysts were characterized by XRD and SEM. Highly crystalline anatase TiO2 powder photocatalyst was obtained. Meanwhile, immobilized TiO2 was less crystalline and agglomerated onto the glass surface. TiO2 powder had higher degradation rate (71%) compared to immobilized TiO2 (52%) due to its chemical stability and larger amount of photocatalyst contacted with methyl orange during the degradation process.
References
Ahmad, R., Ahmad, Z., Khan, A. U., Mastoi, N. R., Aslam, M., & Kim, J. (2016). Photocatalytic systems as an advanced environmental remediation: Recent developments, limitations and new avenues for applications. Journal of Environmental Chemical Engineering,4(4), 4143-4164.
Barton, I., Matejec, V., & Matousek, J. (2016). Photocatalytic activity of nanostructured TiO2 coating on glass slides and optical fibers for methylene blue or methyl orange decomposition under different light excitation. Journal of Photochemistry and Photobiology A: Chemistry,317, 72-80.
Devi, L. G., Kumar, S. G., Reddy, K. M., & Munikrishnappa, C. (2009). Photo degradation of Methyl Orange an azo dye by Advanced Fenton Process using zero valent metallic iron: Influence of various reaction parameters and its degradation mechanism. Journal of Hazardous Materials, 164 (2-3):459-467.
Hanaor, D. A., & Sorrell, C. C. (2010). Review of the anatase to rutile phase transformation. Journal of Materials Science, 46(4), 855-874
Huang, Z., Li, Y., Chen, W., Shi, J., Zhang, N., Wang, X., Zhang, Y. (2017). Modified bentonite adsorption of organic pollutants of dye waste water. Materials Chemistry and Physics, 202:266-276.
Lu, X., Ma, H., Zhang, Q., & Du, K. (2012). Degradation of methyl orange by UV, O3 and UV/O3 systems: analysis of the degradation effects and mineralization mechanism. Research on Chemical Intermediates, 39(9):4189-4203.
Razali, M.H., M.R. Mat Dris, N.N.S. Mohtar Rudin, 2009. Photodegrdation of methyl orange ddye using titanium dioxide photocatalyst. Journal of Sustainability Science and Management, 4: 49-55.
Tanaka, K., M.F.V. Capule, T. Hisanaga, 1991. Effect of crystallinity of TiO2 on its photocatalytic action. Chemical Physics Letters, 187, pp. 73-76.