Removal of Eriochrome Black T DYE from Aqueous Solution by Nickel/Aluminium Layered Double Hydroxide

Authors

  • Nurdiyana Roslan School of Fundamental Science, Universiti Malaysia Terengganu, 21030 Kuala Nerus, Terengganu, Malaysia
  • Mazidah Mamat School of Fundamental Science, Universiti Malaysia Terengganu, 21030 Kuala Nerus, Terengganu, Malaysia
  • Ku Halim Ku Bulat School of Fundamental Science, Universiti Malaysia Terengganu, 21030 Kuala Nerus, Terengganu, Malaysia

DOI:

https://doi.org/10.46754/umtjur.v1i3.81

Keywords:

Adsorption, anionic dye, Freundlich isotherm, layered double hydroxide

Abstract

Batik industry is well known in the East Coast of Malaysia, particularly in Terengganu and Kelantan. This industry consumes a lot of water for the batik making process which contributes to high discharge of wastewater containing excess dye pollutants. Hence, in this study, an anionic clay of nickel/aluminium-layered double hydroxide (NiAL) was investigated as a potential adsorbent for the removal of anionic dye of Eriochrome Black T (EBT). The NiAL was synthesized via self-assembly method and characterization of NiAL was carried out using powder X-ray diffraction (PXRD) and Fourier transform infrared spectrophotometer (FTIR). The composition and morphology of NiAL was further analyzed using carbon, hydrogen, nitrogen, sulphur elemental analyzer (CHNS), thermogravimetric analyzer (TGA) and scanning electron microscope (SEM). The potential of NiAL as an adsorbent for the removal of EBT in aqueous solution was tested at different dosages of NiAL. The adsorption ability was analyzed by using two common adsorption isotherms, which were Langmuir and Freundlich models. The adsorption of EBT onto NiAL was governed by Freundlich isotherm model indicating that the adsorption occurs in heterogeneous system.

References

Adamson, A.W. & Gast A.P. (1997). Physical Chemistry of Surfaces, 6th ed., Wiley Interscience, New York, 808 pp.

Alexandrica, M. C., Silion, M., Hritcu, D., & Popa, M. I. (2015). Layered Double Hydroxides As Adsorbents for Anionic Dye Removal From Aqueous Solutions. Environmental Engineering and Management Journal, 14(2), 381–388.

Allen, S. J., Mckay, G., & Porter, J. F. (2004). Adsorption isotherm models for basic dye adsorption by peat in single and binary component systems. Journal of Colloid and Interface Science, 280(2), 322–333.

Bu, R., Chen, F., Li, J., Li, W. & Yang, F. (2016). Adsorption capability for anionic dyes on 2-hydroxyethylammonium acetate-intercalated layered double hydroxide. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 511, 312 – 319.

Dave, P. N., Kaur, S., & Khosla, E. (2011). Removal of Eriochrome black-T by adsorption on to eucalyptus using green technology. Indian Journal of Chemical Technology,18, 53-60.

Goh, K. H., Lim, T. T., & Dong, Z. (2008). Application of layered double hydroxides for removal of oxyanions: A review. Water Research, 42(6–7), 1343–1368.

Luna, M. D., Flores, E. D., Genuino, D. A., Futalan, C. M., & Wan, M. (2013). Adsorption of Eriochrome Black T (EBT) dye using activated carbon prepared from waste rice hulls-Optimization, isotherm and kinetic studies. Journal of the Taiwan Institute of Chemical Engineers,44(4), 646-653.

Mamat, M., Tagg, T., Khairul, W. M., Abdullah, M. A. A., Mohd Tahir, N., Jubri, Z., & As’ari, R. A. (2014). Behavior of Layered Double Hydroxides Having Different Divalent Transition Metal Groups. Applied Mechanics and Materials, 563, 94–101.

Mittal, A., Kaur, D. & Mittal, J. (2009). Batch and bulk removal of a triarylmethane dye, Fast Green FCF, from wastewater by adsorption over waste materials. Journal of Hazardous Materials, 163, 568 – 577.

Miyata, S. (1983). Anion-Exchange Properties of Hydrotalcite-Like Compounds. Clays and Clay Minerals, 31(4), 305–311.

Muriithi, G. N., Petrik, L. F., Gitari, W. M., & Doucet, F. J. (2017). Synthesis and characterization of hydrotalcite from South African Coal fly ash. Powder Technology, 312, 299–309.

Pang, Y. L., & Abdullah, A. Z. (2013). Current Status of Textile Industry Wastewater Management and Research Progress in Malaysia: A Review. CLEAN - Soil, Air, Water, 41(8), 751-764.

Vijayaraghavan,K., T.V.N. Padmesh, K. Palanivelu, M. Velan,. (2006). Biosorption of nickel (II) ions onto Sargassum wightii: Application of two-parameter and three parameter isotherm models. Journal of Hazardous Materials. B133, 304-308.

Yanming, S., Dongbin, L., Shifeng, L., Lihui, F., & Shuai, C. (2017). Removal of lead from aqueous solution on glutamate intercalated layered double hydroxide. Arabian Journal of Chemistry, 10, S2295–S2301.

Zubair, M., Jarrah, N., Manzar, M. S., Al-Harthi, M., Daud, M., Mu’Azu, N. D., & Haladu, S. A. (2017). Adsorption of eriochrome black T from aqueous phase on MgAl-, CoAl- and NiFe- calcined layered double hydroxides: Kinetic, equilibrium and thermodynamic studies. Journal of Molecular Liquids, 230, 344-352.

Additional Files

Published

2019-07-31

How to Cite

Nurdiyana Roslan, Mazidah Mamat, & Ku Halim Ku Bulat. (2019). Removal of Eriochrome Black T DYE from Aqueous Solution by Nickel/Aluminium Layered Double Hydroxide . Universiti Malaysia Terengganu Journal of Undergraduate Research, 1(3), 79–86. https://doi.org/10.46754/umtjur.v1i3.81